Solvent effect on Hyper-Rayleigh scattering (HRS) first hyperpolarizability of substituted polyene: Part (I)
نویسندگان
چکیده
The first hyperpolarizabilities ?HRS of substituted hexatriene molecules have been carried out to assess the effects bridge length, frequency dispersion as well solvent polarity. These calculations confirm particular behaviour hyperpolarizability ?HRS, depolarization ratio and anisotropy factor a function incident light impact expanding ?-conjugated limit improve .Finally, interplay between ?//, ?vec, dN...N, Egap Kirkwood–Onsager [(?–1)/(2? + 1)] was established.
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ژورنال
عنوان ژورنال: Journal of Fundamental and Applied Sciences
سال: 2021
ISSN: ['1112-9867']
DOI: https://doi.org/10.4314/jfas.v13i3.2